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Materazzi was then signed by Internazionale for €10 million. He finished the 2006–07 season as the top scoring defender of Serie A with 10 goals, including a double away to Siena on 23 April which won the club’s 15th league title with five games remaining. Materazzi was an injury-time substitute for Inter in the 2010 UEFA Champions League Final against Bayern Munich, replacing Diego Milito who scored both of their goals in the 2–0 victory in Madrid. Materazzi declared his retirement from international football in the summer of 2011 and was appointed in the role of ambassador to Inter.